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101.
The sedimentological and geochemical properties of a 7·47 m long laminated sequence from hypersaline Lake Yoa in northern Chad have been investigated, representing a unique, continuous 6100 year long continental record of climate and environmental change in the eastern Central Sahara. These data were used to reconstruct the Mid to Late Holocene history of this currently hyper‐arid region, in order to address the question of whether the Mid Holocene environmental transition from a humid to a dry Sahara was progressive or abrupt. This study involved a suite of analyses, including petrographic and scanning electron microscope examination of thin sections, X‐ray diffraction, X‐radiography, granulometry, loss on ignition and magnetic susceptibility. The potential of micro‐X‐ray fluorescence core scanning was tested at very high resolution. Detailed microscopic investigation revealed the sedimentary processes responsible for the formation of the fine laminations, identified the season during which they were formed, and confirmed their annually rhythmic nature. High‐resolution X‐ray fluorescence core scanning allowed the distinction of each individual lamination over the entire record, opening new perspectives for the study of finely laminated sediment sequences. Geochemical and mineralogical data reveal that, due to decreasing monsoon rainfall combined with continuous and strong evaporation, the hydrologically open and fresh Mid Holocene Lake Yoa slowly evolved into the present‐day hypersaline brine depleted in calcium, which has existed for about the past 1050 years. During the oldest part of the investigated period, Lake Yoa probably contained a permanently stratified lower water column that was nevertheless disrupted relatively frequently by mixing events. Deep‐water anoxia became more stable because of increased salinity‐driven density stratification. In parallel, the sediment grain‐size proxies record a progressive increase of aeolian input in the course of the last 6100 years. Altogether, all geochemical and sedimentological indicators point to a progressive drying of the eastern Central Sahara, strengthening previous conclusions based on palaeoecological indicators.  相似文献   
102.
We have reconstructed the depositional environment of sulphate‐dolomite‐sand‐mud sequences of the Callanna Beds of the late Proterozoic Adelaidean System in three areas of the Willouran Ranges, South Australia. We interpret the Callanna Beds which represent the earliest Adelaidean sediments as having been deposited in a series of discrete shallow cratonic basins. The sequences in all three areas consist of cyclic hypersaline sand‐shale‐carbonate sheets and wedges. Hypersalinity has been inferred from a study of evaporites and their pseudomorphs, which imply basin evolution in sabkha and playa palaeoenvironments. We interpret the Callanna Beds in the Willouran Ranges to have been formed in playa lake or prograding sabkha complexes, that formed in a series of yoked half‐grabens within the tectonic setting of the Adelaide palaeorift.  相似文献   
103.
N2O concentrations and denitrification-related factors (NO3, SO4, dissolved organic carbon (DOC) and CO2) were investigated in the surface groundwater of a catchment in northern Germany, the Fuhrberger Feld Aquifer (FFA). We sampled 79 plots that were selected according to the three criteria of land use, historical land use conversion (1954–1995) and groundwater level. We sampled three sites within each plot. The sampling depth was 0.5 m below the groundwater surface.We found no indication for the occurrence of autotrophic denitrification in the surface groundwater. Heterotrophic denitrification was identified as the main process for N2O accumulation. The variability of N2O concentrations on the plot-scale was extremely high and was poorly explained by the three sampling criteria. Other denitrification-related variables such as NO3, SO4 and DOC were less variable. The selection criteria land use and groundwater level clearly influenced the order of magnitude of N2O concentrations in the surface groundwater. Under arable land, high NO3 concentrations resulted in high N2O concentrations. The surface groundwater under forest and pasture was almost NO3-free and had also very small N2O concentrations. Plots where the distance from the soil surface to the groundwater surface was large (>1 m up to 3.4 m) showed higher N2O concentrations in the surface groundwater than plots where the distance was small (<1 m). A larger distance from the soil surface to the groundwater leads to a longer residence time and more decomposition of DOC in the soil. Consequently the less bioavailable DOC could inhibit the efficiency of the heterotrophic denitrification in the groundwater, yielding more N2O. Elevated organic carbon levels in plots with historic land use conversion (pasture to arable) were very stable and did not influence N2O concentrations. The high within plot variability showed that an upscaling of N2O from the plot-scale to the catchment-scale is possible as long as the groundwater level regime and the land use do not change.  相似文献   
104.
The seasonal cycle in coupled ocean-atmosphere general circulation models   总被引:1,自引:0,他引:1  
We examine the seasonal cycle of near-surface air temperature simulated by 17 coupled ocean-atmosphere general circulation models participating in the Coupled Model Intercomparison Project (CMIP). Nine of the models use ad hoc “flux adjustment” at the ocean surface to bring model simulations close to observations of the present-day climate. We group flux-adjusted and non-flux-adjusted models separately and examine the behavior of each class. When averaged over all of the flux-adjusted model simulations, near-surface air temperature falls within 2?K of observed values over the oceans. The corresponding average over non-flux-adjusted models shows errors up to ~6?K in extensive ocean areas. Flux adjustments are not directly applied over land, and near-surface land temperature errors are substantial in the average over flux-adjusted models, which systematically underestimates (by ~5?K) temperature in areas of elevated terrain. The corresponding average over non-flux-adjusted models forms a similar error pattern (with somewhat increased amplitude) over land. We use the temperature difference between July and January to measure seasonal cycle amplitude. Zonal means of this quantity from the individual flux-adjusted models form a fairly tight cluster (all within ~30% of the mean) centered on the observed values. The non-flux-adjusted models perform nearly as well at most latitudes. In Southern Ocean mid-latitudes, however, the non-flux-adjusted models overestimate the magnitude of January-minus-July temperature differences by ~5?K due to an overestimate of summer (January) near-surface temperature. This error is common to five of the eight non-flux-adjusted models. Also, over Northern Hemisphere mid-latitude land areas, zonal mean differences between July and January temperatures simulated by the non-flux-adjusted models show a greater spread (positive and negative) about observed values than results from the flux-adjusted models. Elsewhere, differences between the two classes of models are less obvious. At no latitude is the zonal mean difference between averages over the two classes of models greater than the standard deviation over models. The ability of coupled GCMs to simulate a reasonable seasonal cycle is a necessary condition for confidence in their prediction of long-term climatic changes (such as global warming), but it is not a sufficient condition unless the seasonal cycle and long-term changes involve similar climatic processes. To test this possible connection, we compare seasonal cycle amplitude with equilibrium warming under doubled atmospheric carbon dioxide for the models in our data base. A small but positive correlation exists between these two quantities. This result is predicted by a simple conceptual model of the climate system, and it is consistent with other modeling experience, which indicates that the seasonal cycle depends only weakly on climate sensitivity.  相似文献   
105.
Humic acids are amphiphilic species whose behavior in aqueous solution suggests that they form pseudomicelles–aggregates akin to the micelles familiar from synthetic surfactant chemistry. It is thought that humic pseudomicelles can be formed by both intramolecular coiling and intermolecular association, depending on the molecular weight, structural characteristics, and polydispersity of the humic acid in question. The process does not feature a critical micelle concentration. Experimental evidence indicates that metal ions enhance the detergent character of dissolved humic acid by facilitating the coiling and folding of the polymer chains. A recently conceived alternative model suggests that humic acids consist of relatively small subunits that associate through weak molecular interactions. This view appears to run counter to certain experimental observations, but deserves careful attention. The strong association between metal ions and solid humic acid makes it possible to use an inexpensive commercial grade for the decontamination of polluted water. A continuous elution process through a column packed with humic acid allows for the removal of both heavy metals and organic xenobiotics from aqueous solution.  相似文献   
106.
Abstract— The gravity‐driven collapse of complex impact craters induces the mass transfer of large rock volumes. In distal parts of a crater, inward movements dominate; whereas in the centre of an impact structure, outward movements occur if the central uplift collapses. The particle trajectory field is centro‐symmetric, which signifies that the conditions for plane‐strain deformation are not fullfilled. Converging particle trajectories can be compensated either by a bulk thickening of inward sliding masses (folding, repetition of rock units along thrust faults, plastic flow) or by the formation of localised radial transpression ridges (RTR) at the edges of individual landslides. In these transpression ridges, material is uplifted to accommodate the converging mass flow. Different modes of uplift are possible including radial folding, lateral overthrusting, and the formation of positive flower structures. A simple geometric model is used to estimate the amount of transpression thickening and bulk thickening of inward sliding masses on the base of volumetric considerations. The existence of RTRs is confirmed by structural investigations at the Siljan impact structure, Sweden, as well as at other complex impact craters on Earth.  相似文献   
107.
108.
von Nordheim  Henning 《Ocean Dynamics》1999,51(10):117-124
Ocean Dynamics - Seit Jahrzehnten, besonders intensiv jedoch seit Verabschiedung der “Konvention zum Schutz der Biologischen Vielfalt” in Rio (1992), werden Meeresgebiete unter Schutz...  相似文献   
109.
110.
Understanding how Amazonian rainforests deal with extended droughts is critical in the face of changing climate. This research analyze the physical properties and the soil water dynamics of a deep soil profile in an area of primary forest in central Amazonia to elucidate these processes under drought and nondrought conditions. Physical soil properties derived from soil cores exhibited a distinctive layer between 480 and 880 cm deep, characterized by higher microporosity and low plant water availability. In situ soil moisture measurements collected during the period from January 2003 through February 2006 and for depths ranging from 10 to 1,430 cm suggest that, in the study site, the top 480 cm of the soil profile satisfied most of the transpirational demands in normal climatological years. However, during exceptionally dry periods, such as the 2005 drought, root uptake occurs below 480 cm. As concluded by previous studies, most of the uptake is concentrated in the first meter of the soil profile: More than 40% of the total demand for transpiration is supplied by the top meter of soil. Because deep root uptake occurred at greater depths than normal during the 2005 drought, our results suggest that this is a fundamental mechanism to cope with prolonged droughts.  相似文献   
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